Stable spirocyclic neutral radicals: aluminium and gallium boraamidinates.
نویسندگان
چکیده
Stable dark red (M = Al) or dark green (M = Ga) neutral radicals {[PhB(mu-NtBu)2]2M} are obtained by the oxidation of their corresponding anions with iodine, and EPR spectra supported by DFT calculations show that the spin density is equally delocalized over all four nitrogen atoms in these spiroconjugated systems.
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عنوان ژورنال:
- Chemical communications
دوره 31 شماره
صفحات -
تاریخ انتشار 2005